SAFETY DATA SHEET    RED STUFF

1. Identification Product number 1000008618 Product identifier 11 OZ RED STUFF LB 24PK WINNER INDUSTRIAL SUPPLY 2375 EAST TROPICANA AVE. LAS VEGAS, NV 89119 United States Company information Company phone General Assistance 951-538-3247 Emergency telephone US 1-866-836-8855 Emergency telephone outside 1-952-852-4646 US Version # 01 Recommended use Lubricant Recommended restrictions None known. 2. Hazard(s) identification Physical hazards Flammable aerosols Category 1 Health hazards Serious eye damage/eye irritation Category 2A Specific target organ toxicity, single exposure Category 3 narcotic effects Aspiration hazard Category 1 OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Extremely flammable aerosol. May be fatal if swallowed and enters airways. Causes serious eye irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing gas. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye protection/face protection. Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazardous to the aquatic environment, acute Category 3 hazard Environmental hazards Hazardous to the aquatic environment, Category 3 long-term hazard Hazard(s) not otherwise classified (HNOC) Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Supplemental information None. 1 / 10 Product name: 11 OZ RED STUFF LB 24PK Product #: 1000008618 Version #: 01 Issue date: 02-18-2016 SDS US 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Acetone 67-64-1 20 - 40 C12-C14 Isoalkanes 68551-19-9 20 - 40 Solvent Naphtha (Petroleum), Light 64742-89-8 20 - 40 Aliphatic Carbon Dioxide 124-38-9 2.5 - 10 n-Heptane 142-82-5 0.1 - 1 Other components below reportable levels 10 - 20 Octane 111-65-9 0.1 - 1 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Eye contact Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Ingestion Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. General information 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Specific methods General fire hazards Extremely flammable aerosol. 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures 2 / 10 Product name: 11 OZ RED STUFF LB 24PK Product #: 1000008618 Version #: 01 Issue date: 02-18-2016 SDS US Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Prevent product from entering drains. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid breathing gas. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. Precautions for safe handling Level 3 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Carbon Dioxide (CAS PEL 9000 mg/m3 124-38-9) 5000 ppm n-Heptane (CAS 142-82-5) PEL 2000 mg/m3 500 ppm Octane (CAS 111-65-9) PEL 2350 mg/m3 500 ppm US. ACGIH Threshold Limit Values Components Type Value Acetone (CAS 67-64-1) STEL 500 ppm TWA 250 ppm Carbon Dioxide (CAS STEL 30000 ppm 124-38-9) TWA 5000 ppm n-Heptane (CAS 142-82-5) STEL 500 ppm TWA 400 ppm Octane (CAS 111-65-9) TWA 300 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Acetone (CAS 67-64-1) TWA 590 mg/m3 250 ppm Carbon Dioxide (CAS STEL 54000 mg/m3 124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm 3 / 10 Product name: 11 OZ RED STUFF LB 24PK Product #: 1000008618 Version #: 01 Issue date: 02-18-2016 SDS US US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value n-Heptane (CAS 142-82-5) Ceiling 1800 mg/m3 440 ppm TWA 350 mg/m3 85 ppm Octane (CAS 111-65-9) Ceiling 1800 mg/m3 385 ppm TWA 350 mg/m3 75 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Acetone (CAS 67-64-1) 25 mg/l Acetone Urine * * - For sampling details, please see the source document. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Appropriate engineering controls Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Hand protection Other Wear suitable protective clothing. If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Respiratory protection Thermal hazards Wear appropriate thermal protective clothing, when necessary. When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point 1.4 °F (-17.0 °C) estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) 0.9 % estimated Flammability limit - upper (%) 7 % estimated Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. 4 / 10 Product name: 11 OZ RED STUFF LB 24PK Product #: 1000008618 Version #: 01 Issue date: 02-18-2016 SDS US Vapor pressure 50 psig @70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. Specific gravity 0.808 estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition No hazardous decomposition products are known. products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. Eye contact Causes serious eye irritation. Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Symptoms related to the physical, chemical and toxicological characteristics Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. Components Species Test Results Acetone (CAS 67-64-1) Dermal Acute LD50 Guinea pig > 7426 mg/kg, 24 Hours > 9.4 ml/kg, 24 Hours Rabbit > 7426 mg/kg, 24 Hours > 9.4 ml/kg, 24 Hours Inhalation LC50 Rat 55700 ppm, 3 Hours 132 mg/l, 3 Hours 50.1 mg/l Oral LD50 Rat 5800 mg/kg 5 / 10 Product name: 11 OZ RED STUFF LB 24PK Product #: 1000008618 Version #: 01 Issue date: 02-18-2016 SDS US Components Species Test Results 2.2 ml/kg n-Heptane (CAS 142-82-5) Dermal Acute LD50 Rabbit > 2000 mg/kg, 24 Hours Inhalation LC50 Rat > 29.29 mg/l, 4 Hours Oral LD50 Rat > 5000 mg/kg Octane (CAS 111-65-9) Dermal Acute LD50 Rabbit > 2000 mg/kg, 24 Hours Inhalation LC50 Rat > 24.88 mg/l, 4 Hours Oral LD50 Rat > 5000 mg/kg Solvent Naphtha (Petroleum), Light Aliphatic (CAS 64742-89-8) Dermal Acute LD50 Rabbit > 1900 mg/kg, 24 Hours Inhalation LC50 Rat > 5000 mg/m3, 4 Hours > 4980 mg/m3 > 4980 mg/m3, 4 Hours > 4.96 mg/l, 4 Hours Oral * Estimates for product may be based on additional component data not shown. LD50 Rat 4820 mg/kg Skin corrosion/irritation Not applicable. Serious eye damage/eye Causes serious eye irritation. irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not available. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US. National Toxicology Program (NTP) Report on Carcinogens Not available. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. 6 / 10 Product name: 11 OZ RED STUFF LB 24PK Product #: 1000008618 Version #: 01 Issue date: 02-18-2016 SDS US Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. Components Species Test Results Acetone (CAS 67-64-1) Aquatic Crustacea EC50 Water flea (Daphnia magna) 21.6 - 23.9 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 4740 - 6330 mg/l, 96 hours (Oncorhynchus mykiss) * Estimates for product may be based on additional component data not shown. n-Heptane (CAS 142-82-5) Aquatic Fish LC50 Mozambique tilapia (Tilapia 375 mg/l, 96 hours mossambica) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone -0.24 n-Heptane 4.66 Octane 5.18 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Local disposal regulations Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Contaminated packaging 14. Transport information DOT UN number UN1950 UN proper shipping name Aerosols, flammable, (each not exceeding 1 L capacity) Class 2.1 Transport hazard class(es) Subsidiary risk - Label(s) 2.1 Packing group Not applicable. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Special provisions N82 Packaging exceptions 306 Packaging non bulk None Packaging bulk None 7 / 10 Product name: 11 OZ RED STUFF LB 24PK Product #: 1000008618 Version #: 01 Issue date: 02-18-2016 SDS US This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN number UN1950 UN proper shipping name Aerosols, flammable Class 2.1 Transport hazard class(es) Subsidiary risk - Label(s) 2.1 Packing group Not applicable. Environmental hazards No. ERG Code 10L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Passenger and cargo Allowed with restrictions. aircraft Other information Cargo aircraft only Allowed with restrictions. Packaging Exceptions LTD QTY IMDG UN number UN1950 UN proper shipping name AEROSOLS Class 2.1 Transport hazard class(es) Subsidiary risk - Label(s) 2.1 Packing group Not applicable. Marine pollutant No. Environmental hazards EmS F-D, S-U Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Packaging Exceptions LTD QTY Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 8 / 10 Product name: 11 OZ RED STUFF LB 24PK Product #: 1000008618 Version #: 01 Issue date: 02-18-2016 SDS US 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Acetone (CAS 67-64-1) Solvent Naphtha (Petroleum), Light Aliphatic (CAS 64742-89-8) US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Carbon Dioxide (CAS 124-38-9) n-Heptane (CAS 142-82-5) Octane (CAS 111-65-9) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Carbon Dioxide (CAS 124-38-9) n-Heptane (CAS 142-82-5) Octane (CAS 111-65-9) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Carbon Dioxide (CAS 124-38-9) 9 / 10 Product name: 11 OZ RED STUFF LB 24PK Product #: 1000008618 Version #: 01 Issue date: 02-18-2016 SDS US n-Heptane (CAS 142-82-5) Octane (CAS 111-65-9) US. Rhode Island RTK Acetone (CAS 67-64-1) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Ethyl Benzene (CAS 100-41-4) Listed: June 11, 2004 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) No Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical No Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances No (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 02-18-2016 Version # 01 We cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Disclaimer Revision information Product and Company Identification: Alternate Trade Names 10 / 10 Product name: 11 OZ RED STUFF LB 24PK Product #: 1000008618 Version #: 01 Issue date: 02-18-2016 SDS US