SECTION 2) HAZARDS IDENTIFICATION
  Classification:
  Specific
                                 Target Organ Toxicity -Single Exposure (Respiratory Tract Irritation) - Category 3
  Skin Irritation
                                 - Category 2
  Eye Irritation - Category 2A
  Aerosols Category 1
  Acute toxicity, Oral - Category 5
  Pictograms:
  Signal
                                 Word:
  Danger
  Hazardous Statements - Physical:
  H222
                                 - Extremely flammable aerosol
  H229 - Pressurised container: May burst if heated
  Hazardous
                                 Statements - Health:
  H335 - May cause respiratory irritation
  H315 - Causes
                                 skin irritation
  H319 - Causes serious eye irritation
  H303 - May be harmful
                                 if swallowed
  Precautionary Statements - General:
  P101 - If medical advice
                                 is needed, have product container or label at hand.
  P102 - Keep out of reach of children.
  P103 - Read label before use.
  Precautionary Statements - Prevention:
  P261
                                 - Avoid breathing dust/fume/gas/mist/vapors/spray.
  P271 - Use only outdoors or in a well-ventilated
                                 area.
  SAFETY DATA SHEET 
  Oct 14, 2015
  WINNER
                                 INDUSTRIAL SUPPLY, INC.
  Product ID: SAFETY SHIELD
  ADDRESS:
  `154-A
                                 WEST FOOTHILL BLVD
  UPLAND ,CA. 91786
  PHONE:909-886-9466
  SECTION
                                 1) CHEMICAL PRODUCT AND SUPPLIER'S IDENTIFICATION
  QUA01201
  Version: 1.0
                                 Date Printed: Oct 14, 2015
  Supersedes Date: N.A.
  SAFETY
                                 Shield Glass Treatment 
  Emergency Phone:
  Information Phone Number:
                                 CHEMTREC US : 1-800-424-9300, INTERNATIONAL CALLS : 1-703-527-3887
  1-877-320-4747
                                 Fax:
  Product/Recommended Uses: Glass Treatment
  QUA01201
                                 Page 1 of 8
  P233 - Keep container tightly closed. P264 - Wash thoroughly after handling.
  P280 - Wear protective gloves/protective clothing/eye protection/face protection.
  P210
                                 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  P211
                                 - Do not spray on an open flame or other ignition source.
  P251 - Do not pierce or burn, even after
                                 use.
  Precautionary Statements - Response:
  P304 + P340 - IF INHALED: Remove
                                 person to fresh air and keep comfortable for breathing.
  P312 - Call a POISON CENTER/doctor if you
                                 feel unwell.
  P302 + P352 - IF ON SKIN: Wash with plenty of water.
  P321
                                 - For specific treatment see section 4.
  P332 + P313 - If skin irritation occurs: Get medical advice/attention.
                                 P362 + P364 - Take off contaminated clothing. And wash it before reuse.
  P305
                                 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
                                 do. Continue rinsing.
  P337 + P313 - If eye irritation persists: Get medical advice/attention.
                                 Precautionary Statements - Storage:
  P403 + P405 - Store in a well-ventilated
                                 place. Store locked up.
  P410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding
                                 50 °C/122 °F.
  Precautionary Statements - Disposal:
  P501 - Dispose
                                 of contents/container to disposal recycling center. Under RCRA it is the responsibility of the user of the product to determine
                                 at the time of disposal whether the product meets RCRA criteria for hazardous waste. Waste management should be in full compliance
                                 with federal, state and local laws.
  SECTION 4)  FIRST-AID MEASURES
  Inhalation:
                                 Remove source of exposure or move person to fresh air and keep comfortable for breathing.
  If
                                 exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
  Eliminate all ignition sources if safe
                                 to do so.
  Skin Contact:
  Take off contaminated clothing, shoes and leather
                                 goods (e.g. watchbands, belts). Wash with plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin
                                 irritation occurs: Get medical advice/attention. Wash contaminated clothing before re-use.
  IF exposed
                                 or concerned: Get medical advice/attention.
  Eye Contact:
  Remove source
                                 of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while
                                 holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes.
                                 Take care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical
                                 advice/attention. Ingestion:
  Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. If
                                 vomiting occurs naturally, lie on your side, in the recovery position. Do not give anything.
  SECTION
                                 5)  FIRE-FIGHTING MEASURES
  SECTION 3)  COMPOSITION / INFORMATION ON INGREDIENTS
  CAS Chemical Name % By Weight
  0000064-17-5 ETHYL ALCOHOL 41% - 68%
  0000067-64-1
                                 ACETONE 18% - 30%
  0000067-63-0 ISOPROPYL ALCOHOL 5% - 11%
  0068476-86-8
                                 Petroleum gases, liquefied, sweetened 3% - 6%
  0000124-38-9 CO2 0.1% - 2%
  QUA01201
                                 Page 2 of 8
  Suitable Extinguishing Media:
  Dry chemical, foam, carbon dioxide
                                 is recommended. Water spray is recommended to cool or protect exposed materials or structures. Carbon dioxide can displace
                                 oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface
                                 is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
  Do
                                 not direct a solid stream of water or foam into hot, burning pools this may results in frothing and increase fire intensity.
                                 Unsuitable Extinguishing Media:
  Not available.
  Specific
                                 Hazards in Case of Fire:
  Contents under pressure. Keep away from ignition sources and open flames.
                                 Exposure of containers to extreme heat and flames can cause them to rupture often with violent force.Product is highly flammable
                                 and forms explosive mixtures with air, oxygen, and all oxidizing agents. Vapors are heavier than air and may travel along
                                 surfaces to remote ignition sources and flash back.
  During a fire, irritating and highly toxic gases
                                 may be generated during combustion or decomposition.  High temperatures can cause sealed containers to rupture due to
                                 a build up of internal pressures.  Cool with water.
  DO NOT cut, drill, grind, or weld near
                                 full, partially full, or empty product containers.
  Container could potentially burst or be punctured
                                 upon mechanical impact, releasing flammable vapors.
  Fire-Fighting Procedures:
  Isolate
                                 immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers
                                 from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect
                                 personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised
                                 when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.
  Dispose
                                 of fire debris and contaminated extinguishing water in accordance with official regulations.
  Special
                                 Protective Actions:
  Wear protective pressure self-contained breathing apparatus (SCBA) and full
                                 turnout gear.
  SECTION 6)  ACCIDENTAL RELEASE MEASURES
  Emergency Procedure:
                                 ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
  Do
                                 not touch or walk through spilled material.
  Isolate hazard area and keep unnecessary people away.
                                 Remove all possible sources of ignition in the surrounding area. Notify authorities if any exposure to the general public
                                 or the environment occurs or is likely to occur.
  If spilled material is cleaned up using a regulated
                                 solvent, the resulting waste mixture may be regulated.
  Recommended Equipment:
  Positive
                                 pressure, full-facepiece self-contained breathing apparatus (SCBA), or positive pressure supplied air respirator with escape
                                 SCBA (NIOSH approved). Personal Precautions:
  Avoid breathing vapor. Avoid contact with skin, eye
                                 or clothing. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged
                                 containers or spilled materials unless wearing appropriate protective clothing. Environmental Precautions:
  Stop
                                 spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage
                                 systems and natural waterways by using sand, earth, or other appropriate barriers. Methods and Materials for Containment and
                                 Cleaning Up:
  Cover spills with inert absorbent and place in closed chemical waste containers.
                                 SECTION 7)  HANDLING AND STORAGE
  General:
  Wash
                                 hands after use. Do not get in eyes, on skin or on clothing. Do not breathe vapors or mists. Use good personal hygiene practices.
                                 Eating, drinking and smoking in work areas is prohibited. Remove contaminated clothing and protective equipment before entering
                                 eating areas.
  Eyewash stations and showers should be available in areas where this material is used
                                 and stored.
  Ventilation Requirements:
  Use only with adequate ventilation
                                 to control air contaminants to their exposure limits. The use of local ventilation is recommended to control emissions near
                                 the source.
  QUA01201 Page 3 of 8
  Storage Room Requirements:
  Keep
                                 container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight,
                                 strong oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers
                                 securely sealed when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have
                                 been opened must be carefully resealed to prevent leakage. Empty containers retain residue and may be dangerous. Use non-sparking
                                 ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this product
                                 is used and stored.
  Do not cut, drill, grind, weld or perform similar operations on or near containers.
                                 Do not pressurize containers to empty them.
  Store at temperatures below 120°F.
  SECTION
                                 8)  EXPOSURE CONTROLS/PERSONAL PROTECTION
  Eye Protection:
  Wear eye
                                 protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids.
                                 If additional protection is needed for entire face, use in combination with a face shield. Skin Protection:
  Use
                                 of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC,
                                 neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration
                                 of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated
                                 gloves should be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile
                                 rubber is recommended to avoid skin sensitization. The type of protective equipment must be selected according to the concentration
                                 and amount of the dangerous substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated
                                 material, which cannot be decontaminated. Respiratory Protection:
  If engineering controls do not
                                 maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection program that meets
                                 or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective equipment suppliers.
                                 Appropriate Engineering Controls:
  Provide exhaust ventilation or other engineering controls to keep
                                 the airborne concentrations of vapors below their respective threshold limit value.
  Chemical Name
                                 OSHA TWA   (ppm)
  OSHA     TWA    (mg/m3)
  OSHA  
                                 STEL (ppm)
  OSHA   STEL   (mg/m3)
  OSHA Tables (Z1,
                                 Z2, Z3) 
            OSHA     Carcinogen
                                  OSHA   Skin designation
  NIOSH    TWA  
                                 (ppm)
  NIOSH    TWA    (mg/m3)
  NIOSH   
                                 STEL (ppm)
  NIOSH    STEL   (mg/m3)
            
                                 NIOSH   Carcinogen
  ACETONE 1000 2400 1 250 590 CO2 5000 9000 1 5000 9000 30000 54000 ETHYL
                                 ALCOHOL 1000 1900 1 1000 1900 ISOPROPYL ALCOHOL 400 980 1 400 980 500 1225 Petroleum gases, liquefied, sweetened 500 2000
                                 1
  Chemical Name ACGIH  TWA    (ppm)
  ACGIH  TWA   
                                 (mg/m3)
  ACGIH   STEL (ppm)
  ACGIH   STEL  (mg/m3)
                                 ACETONE 500 1188 750 1782 CO2 5000 9000 30000 54000 ETHYL ALCOHOL 1000 ISOPROPYL ALCOHOL 200 400 Petroleum gases, liquefied,
                                 sweetened
  SECTION 9)  PHYSICAL AND CHEMICAL PROPERTIES
  Physical and
                                 Chemical Properties
  Density 6.50126 lb/gal
  Density VOC 4.70890 lb/gal
                                 QUA01201 Page 4 of 8
  Appearance Clear Liquid 
  Odor
                                 Threshold N.A. 
  Odor Description Alcohol 
  pH N.A. 
  Flammability
                                 N/A 
  Water Solubility N.A. 
  Flash Point Symbol N.A. 
  Flash
                                 Point N.A. 
  Viscosity N.A. 
  Lower Explosion Level N.A. 
  Upper
                                 Explosion Level N.A. 
  Vapor Pressure N.A. 
  Vapor Density N.A. 
  Freezing Point N.A. 
  Melting Point N.A. 
  Low Boiling
                                 Point N.A. 
  High Boiling Point N.A. 
  Auto Ignition Temp N.A. 
  Evaporation Rate N.A. 
  VOC Composite Partial Pressure N.A. 
  VOC
                                 Actual 564.26737 g/l
  VOC Actual 4.70890 lb/gal
  % VOC 72.43055% 
  SECTION 10)  STABILITY AND REACTIVITY
  Stability:
  Material
                                 is stable at standard temperature and pressure.
  Conditions to Avoid:
  Keep
                                 away from direct sunlight and other sources of ignition. Dropping containers may cause bursting. Hazardous Reactions/Polymerization:
                                 Will not occur
  Incompatible Materials:
  Avoid strong
                                 oxidizers, reducers, acids, and alkalis.
  Hazardous Decomposition Products:
  No
                                 data available.
  SECTION 11)  TOXICOLOGICAL INFORMATION
  Skin Corrosion/Irritation:
                                 Prolonged or repeated contact with this product may dry and/or defat the skin. This product may be harmful
                                 if it is absorbed through the skin.
  Causes skin irritation
  Serious Eye
                                 Damage/Irritation:
  Eye contact may lead to permanent damage if not treated promptly.
  Liquid
                                 or vapors may irritate the eyes.
  Symptoms may include stinging, tearing, redness, swelling, and
                                 blurred vision. Eye contact may lead to permanent damage if not treated promptly.
  Causes serious
                                 eye irritation
  Respiratory/Skin Sensitization:
  No Data Available
 
                                 QUA01201 Page 5 of 8
  0000067-64-1 ACETONE
  LC50 (male
                                 rat): 30000 ppm (4-hour exposure); cited as 71000 mg/m3 (4-hour exposure) (29) LC50 (male mouse): 18600 ppm (4-hour exposure);
                                 cited as 44000 mg/m3 (4-hour exposure) (29)
  LD50 (oral, female rat): 5800 mg/kg (24) LD50 (oral,
                                 mature rat): 6700 mg/kg (cited as 8.5 mL/kg) (31) LD50 (oral, newborn rat): 1750 mg/kg (cited as 2.2 mL/kg) (31) LD50 (oral,
                                 mouse): 3000 mg/kg (32,unconfirmed) LD50 (dermal, rabbit): Greater than 16000 mg/kg cited as 20 mL/kg) (30)
  0000064-17-5
                                 ETHYL ALCOHOL
  LC50 (mouse): Approximately 21000 ppm (4-hour exposure); cited as 39 g/m3 (4-hour
                                 exposure) (1, unconfirmed)
  LD50 (oral, rat): 7060 mg/kg (41); 10600 mg/kg (41); 13660 mg/kg (37)
                                 LD50 (oral, mouse): 3450 mg/kg (1, unconfirmed) LD50 (oral, guinea pig): 5560 mg/kg (37)
  0000067-63-0
                                 ISOPROPYL ALCOHOL
  LC50 (rat): 17000 ppm (4-hour exposure); cited as 12000 ppm (8-hour exposure)
                                 (18)
  LD50 (oral, male rat):  4710 mg/kg (cited as 6.0 mL/kg) (19) LD50 (oral, mouse): 3600
                                 mg/kg (20, unconfirmed) LD50 (dermal, rabbit): 12870 mg/kg (cited as 16.4 mL/kg) (14)
  Potential
                                 Health Effects - Miscellaneous
  0000064-17-5 ETHYL ALCOHOL
  The following
                                 medical conditions may be aggravated by exposure: liver disease. Tests in some laboratory animals indicate this compound may
                                 have embryotoxic activity. Tests in animals demonstrate reproductive toxicity. Ingestion may cause any of the following: stupor
                                 (central nervous system depression), gastrointestinal irritation. If absorbed through the skin, may be: harmful.
  0000067-63-0
                                 ISOPROPYL ALCOHOL
  The following medical conditions may be aggravated by exposure: dermatitis, respiratory
                                 disease. Developmental toxicity was seen in rat?s offspring at doses that were maternally toxic. Contact will cause moderate
                                 to severe redness and swelling, itching, tingling sensation, painful burning. May cause injury to the cornea of the eyes.
                                 Prolonged or repeated exposure may cause damage to any of the following organs/systems: liver. Ingestion studies on laboratory
                                 animals showed that very high oral doses caused increased liver and kidney weights.
  0000067-64-1
                                 ACETONE
  The following medical conditions may be aggravated by exposure: lung disease, eye disorders,
                                 skin disorders. Overexposure may cause damage to any of the following organs/systems: blood, central nervous system, eyes,
                                 kidneys, liver, respiratory system, skin.
  Germ Cell Mutagenicity:
  No Data
                                 Available
  Carcinogenicity:
  No Data Available
  Reproductive
                                 Toxicity:
  No Data Available
  Specific Target Organ Toxicity - Single Exposure:
                                 May cause respiratory irritation
  Specific Target Organ Toxicity - Repeated
                                 Exposure:
  Prolonged exposure may cause damage to her central nervous system, lungs, skin and eyes.
                                 Aspiration Hazard:
  No Data Available
  Acute Toxicity:
                                 If inhaled, may cause dizziness, nausea, upper respiratory irritation, drowsiness, mental depression
                                 or narcosis, difficulty in breathing, irregular heart beats.
  SECTION 12)  ECOLOGICAL INFORMATION
                                 Toxicity:
  No Data Available
  Persistence and Degradability:
                                 No data available.
  Bio-accumulative Potential:
  No
                                 data available.
  QUA01201 Page 6 of 8
  Mobility in Soil:
  No
                                 data available.
  Other Adverse Effects:
  No data available.
  Bio-accumulative
                                 Potential
  0000067-64-1 ACETONE
  Does not bioaccumulate
  Persistence
                                 and Degradability
  0000067-64-1 ACETONE
  91% readily biodegradable, Method:
                                 OECD Test Guideline 301B
  SECTION 13)  DISPOSAL CONSIDERATIONS
  Waste
                                 Disposal:
  Under RCRA it is the responsibility of the user of the product to determine at the time
                                 of disposal whether the product meets RCRA criteria for hazardous waste. Waste management should be in full compliance with
                                 federal, state and local laws.
  Empty Containers retain product residue which may exhibit hazards
                                 of material, therefore do not pressurize, cut, glaze, weld or use for any other purposes. Return drums to reclamation centers
                                 for proper cleaning and reuse.
  SECTION 14)  TRANSPORT INFORMATION
  U.S.
                                 DOT Information:
  Ground Transportation: (Continental United States, Canada & Mexico): Limited
                                 Quantity
  IMDG Information:
  Shipping Name: Aerosols, flammable UN/NA #:
                                 1950 Hazard Class: 2.1 Required Placard: Limited Quantity
  Marine Pollutant: No data available
                                  IATA Information:
  We do NOT recommend this product to be shipped via air.
                                 It would need to be repacked by an authorized packing company and the DG would have to be completed by a licensed hazardous
                                 material shipping company.
  SECTION 15)  REGULATORY INFORMATION
  CAS
                                 Chemical Name % By Weight Regulation List 0000064-17-5 ETHYL ALCOHOL 41% - 68% SARA312,VOC,TSCA 0000067-64-1 ACETONE 18% -
                                 30% CERCLA,SARA312,VOC_exempt,TSCA,RCRA 0000067-63-0 ISOPROPYL ALCOHOL 5% - 11% SARA312,SARA313,VOC,TSCA 0068476-86-8 Petroleum
                                 gases, liquefied, sweetened 3% - 6% SARA312,VOC,TSCA 0000124-38-9 CO2 0.1% - 2% SARA312,TSCA
  SECTION
                                 16)  OTHER INFORMATION
  Glossary:
  QUA01201 Page 7 of 8
  ACGIH-
                                 American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; Canadian TDG- Canadian
                                 Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical Transportation Emergency Center (US);
                                 CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC- Equivalent Concentration; EH40 (UK)- HSE
                                 Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and Community Right-To-Know Act; ESL- Effects screening
                                 levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; LD- Lethal Dose; NFPA- National Fire Protection
                                 Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health Administration, US Department of Labor;
                                 PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization Act; SARA 313- Superfund Amendments
                                 and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short Term Exposure Limit; TCEQ - Texas
                                 Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA- Toxic Substances Control Act Public Law 94-469; TWA
                                 - Time Weighted Value; US DOT- US Department of Transportation; WHMIS- Workplace Hazardous Materials Information System.
                                  Version 1.0:
  Revision Date: Oct 14, 2015
  First Edition.
                                  DISCLAIMER
  To the best of our knowledge, the information contained herein
                                 is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the
                                 accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole
                                 responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards
                                 are described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this
                                 product as currently formulated, and is based on the information available at this time.  Addition of reducers or other
                                 additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are
                                 outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this
                                 information.
  QUA01201 Page 8 of 8