Revision: 04/16/2015 Printed: 07/07/2015 Page: 1 Miracle H.D. Degreaser SAFETY DATA SHEET Supersedes Revision: 03/11/2015 Product Code: BU1583 Product Name: Miracle H.D. Degreaser Company Name: Winner Industrial Supply 154 "A" Foothill Blvd #149 Upland, CA 91786 Emergency Contact: infotrac #107557 (800)535-5053 Information: vincent@winnerchemicals.com (909)886-9466 Recommended Use: Hard Surface Cleaner/Degreaser Intended Use: For sale to, use and storage by service persons only. 1. Product and Company Identification 2. Hazards Identification Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Keep out of reach of children. Wear protective gloves, protective clothing, eye protection, face protection. GHS Precaution Phrases: If swallowed: Immediately call a Poison Center or doctor. If on skin (or in hair): Wash with plenty of soap and water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. GHS Response Phrases: Store in cool dry place at room temperature away from direct sunlight. Dispose of contents and container according to the local, city, state and federal regulations. GHS Storage and Disposal Phrases: Harmful if swallowed. Causes mild skin irritation. Causes serious eye irritation. GHS Hazard Phrases: Acute Toxicity: Oral, Category 4 Skin Corrosion/Irritation, Category 3 Serious Eye Damage/Eye Irritation, Category 2A GHS Signal Word: Warning Potential Health Effects Prolonged or repeated skin contact may cause defatting and dermatitis. (Acute and Chronic): Causes eye irritation. May cause transient corneal injury. Causes eye burns. Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Eye Contact: Skin Contact: Causes skin irritation. May be harmful if absorbed through the skin. Causes skin burns. May cause kidney damage. Harmful if swallowed. Causes burns. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion: May be harmful if inhaled. Inhalation of a mist of this material may cause respiratory tract irritation. Inhalation: GHS format Revision: 04/16/2015 Printed: 07/07/2015 Page: 2 Miracle H.D. Degreaser SAFETY DATA SHEET Supersedes Revision: 03/11/2015 CAS # Hazardous Components (Chemical Name) 3. Composition/Information on Ingredients Concentration 112-34-5 Diethylene glycol monobutyl ether Proprietary 6834-92-0 Silicic acid (H2SiO3), Disodium salt Proprietary 166736-08-9 Oxirane, methyl-, polymer with oxirane, mono(2-propylheptyl) ether Proprietary 67-63-0 Isopropyl alcohol Proprietary In Case of Inhalation: 4. First Aid Measures Emergency and First Aid Procedures: Note to Physician: Treat symptomatically and supportively. Signs and Symptoms Of Burning sensation, Cough, Wheezing, Laryngitis, Shortness of breath. Exposure: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Continue rinsing eyes during transport to hospital. In Case of Eye Contact: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. In Case of Skin Contact: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. In Case of Ingestion: Remove from exposure and move to fresh air immediately. Get medical aid. 5. Fire Fighting Measures Flash Pt: NE As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Fire Fighting Instructions: Flammable Properties and No data available. Hazards: Autoignition Pt: NE Explosive Limits: LEL: N/A N.E. UEL: N/A N.E. Suitable Extinguishing Media:In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. 6. Accidental Release Measures Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Steps To Be Taken In Case Material Is Released Or Spilled: Environmental Precautions: Avoid release to the environment. 7. Handling and Storage Avoid breathing dust, mist, or vapor. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Precautions To Be Taken in Handling: Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Precautions To Be Taken in Storing: GHS format Revision: 04/16/2015 Printed: 07/07/2015 Page: 3 Miracle H.D. Degreaser SAFETY DATA SHEET Supersedes Revision: 03/11/2015 8. Exposure Controls/Personal Protection CAS # Partial Chemical Name OSHA TWA ACGIH TWA Other Limits 112-34-5 Diethylene glycol monobutyl ether No data. No data. No data. 6834-92-0 Silicic acid (H2SiO3), Disodium salt No data. No data. No data. 166736-08-9 Oxirane, methyl-, polymer with oxirane, No data. No data. mono(2-propylheptyl) ether No data. PEL: 400 ppm TLV: 200 ppm STEL: 400 ppm 67-63-0 Isopropyl alcohol No data. Respiratory Equipment Always use a NIOSH approved respirator when necessary. (Specify Type): Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Face shield and safety glasses. Eye Protection: Protective Gloves: Wear appropriate protective gloves to prevent skin exposure. Other Protective Clothing: Wear appropriate protective clothing to prevent skin exposure. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Engineering Controls (Ventilation etc.): Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Work/Hygienic/Maintenance Practices: 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: NE Boiling Point: > 212.00 F Decomposition Temperature: NE Autoignition Pt: NE Flash Pt: NE Explosive Limits: LEL: N/A N.E. UEL: N/A N.E. Specific Gravity (Water = 1): 1.042 Density: ~ 8.69 lbs/gal Appearance and Odor: Blue color liquid with solvent odor. Bulk density: NE Vapor Pressure (vs. Air or mm Hg): NE Vapor Density (vs. Air = 1): NE Evaporation Rate: NE Solubility in Water: 100% Percent Volatile: No data. VOC / Volume: < 4.0000 G/L Saturated Vapor Concentration: NE Viscosity: NP pH: 11.5 - 12.5 GHS format Revision: 04/16/2015 Printed: 07/07/2015 Page: 4 Miracle H.D. Degreaser SAFETY DATA SHEET Supersedes Revision: 03/11/2015 Heat Value: NE Particle Size: NE Corrosion Rate: NE 10. Stability and Reactivity Conditions To Avoid - None. Instability: Stability: Unstable [ ] Stable [ X ] Incompatibility - Materials To Cationic materials, strong oxidizers, strong acidic materials. Avoid: Hazardous Decomposition Or CO, CO2. Byproducts: Possibility of Hazardous Will occur [ ] Will not occur [ X ] Reactions: Conditions To Avoid - None. Hazardous Reactions: CAS # Hazardous Components (Chemical Name) NTP 11. Toxicological Information Toxicological Information: No data available. CAS# 112-34-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Carcinogenicity. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. CAS# 67-63-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Carcinogenicity/Other Information: IARC ACGIH OSHA CAS# 6834-92-0: Acute toxicity, LD50, Oral, Mouse, 770.0 MG/KG. Results: Kidney, Ureter, Bladder:Changes in tubules (including acute renal failure, acute tubular necrosis). Kidney, Ureter, Bladder: Changes in bladder weight. Nutritional and Gross Metabolic:Weight loss or decreased weight gain. - Toxicology Letters., Elsevier Science Pub. B.V., POB 211, 1000 AE, Amsterdam 1000 AE Netherlands, Vol/p/yr: 31(Suppl),, 1986 112-34-5 Diethylene glycol monobutyl ether n.a. n.a. n.a. n.a. 6834-92-0 Silicic acid (H2SiO3), Disodium salt n.a. n.a. n.a. n.a. 166736-08-9 Oxirane, methyl-, polymer with oxirane, mono(2-propylheptyl) ether n.a. n.a. n.a. n.a. 67-63-0 Isopropyl alcohol n.a. 3 A4 n.a. GHS format Revision: 04/16/2015 Printed: 07/07/2015 Page: 5 Miracle H.D. Degreaser SAFETY DATA SHEET Supersedes Revision: 03/11/2015 No data available. 12. Ecological Information Persistence and No data available. Degradability: Dispose of contents and container according to the local, city, state and federal regulations. Waste Disposal Method: 13. Disposal Considerations 14. Transport Information DOT Proper Shipping Name: Not regulated as a hazardous material. DOT Hazard Class: UN/NA Number: LAND TRANSPORT (US DOT): TDG Shipping Name: Not Regulated. LAND TRANSPORT (Canadian TDG): ADR/RID Shipping Name: Not Regulated. LAND TRANSPORT (European ADR/RID): IMDG/IMO Shipping Name: Not Regulated. MARINE TRANSPORT (IMDG/IMO): ICAO/IATA Shipping Name: Not Regulated. AIR TRANSPORT (ICAO/IATA): 15. Regulatory Information CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 112-34-5 Diethylene glycol monobutyl ether CAA HAP,ODC: HAP; CWA NPDES: No; TSCA: Yes - Inventory, 4 Test; CA PROP.65: No; CA TAC, Title 8: TAC 6834-92-0 Silicic acid (H2SiO3), Disodium salt CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No 166736-08-9 Oxirane, methyl-, polymer with oxirane, mono(2-propylheptyl) ether CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No 67-63-0 Isopropyl alcohol CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory, 4 Test; CA PROP.65: No; CA TAC, Title 8: TAC, Title 8 GHS format Revision: 04/16/2015 Printed: 07/07/2015 Page: 6 Miracle H.D. Degreaser SAFETY DATA SHEET Supersedes Revision: 03/11/2015 16. Other Information Additional Information About PPE C: safety glasses, gloves, apron. This Product: Hazard Rating System: Instability Special Hazard Health Flammability HEALTH FLAMMABILITY PPE PHYSICAL The manufacturer believes the data set forth are accurate and makes no warranty with respects thereto and disclaims all liability for reliance thereon. Such data are offered solely for consideration, investigation and verification. Also, the data set forth is for the concentrated finished product. All lab samples are for experimental purposes only and used at the customers discretion. Company Policy or Disclaimer: 2 0 0 C 2 0 0 Revision Date: 04/16/2015 HMIS: NFPA: GHS format