SAFETY DATA SHEET (SDS)
PERMITH
Manufactured
For: SUNGRO PRODUCTS
Issue Date: 25-Jun-2015
810 E. 18TH ST.
LOS ANGELES, CA
90021
Tel: 213-747-4125
Fax: 213-747-0942
E: sales@sungroproducts.com
This Material Safety Data Sheet contains environmental, health
and toxicology information for your employees. Please make sure this information is given to them. It also contains information
to help you meet community Right To Know emergency response reporting requirements under SARA TITLE III and many other laws.
If you resell this product, this SDS must be given to the buyer or the information incorporated in your SDS.
Section
1: Product Identification |
|
Product identifier
Product Name:
PERMITH
EPA Registration Number:
1021-1740-84396
Other means
of identification
Part Code:
26575
Recommended use of the chemical and restrictions on use:
Recommended Use:
An
insecticide for use as a space, area, and contact spray.
Details of the
supplier of the safety data sheet
Manufacturer Address:
Sungro Products,
LLC.
810 E. 18th St.
Los Angeles, CA 90021
FAX #: (213)747-0942
Telephone Number: (800)463-9179, or (213) 747-4125
E-Mail Address: sales@sungroproducts.com
Emergency
telephone numbers:
24 Hour TRANSPORTATION Emergency: INFOTRAC®: (800) 535-5053 - Contract
#78479
International:
(352) 323-3500
24 Hour MEDICAL Emergency: Safety Call®: (888) 740-8712, or (952)
852-9509
Comments:
SUNGRO PRODUCTS
Hours of operation are 7:30 am to 4:00 pm PCT.
For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to
(888) 740-8712, or (952) 852-9509.
Section 2: Hazard(s) Identification
Classification
OSHA Regulatory Status:
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Acute
Toxicity: Inhalation
Category 4
Label elements
Emergency Overview
WARNING
Hazard statements
• H332 –
Harmful if inhaled
• H400 – Very toxic to aquatic life
• H410 –
Very toxic to aquatic life with long lasting effects
Appearance: Milky
white
Physical state: Liquid
Odor: Slight solvent
Precautionary Statements - Prevention:
P261- Avoid
breathing fume/mist/vapor spray
P271 – Use only outdoors or in a well-ventilated area
P272 – Contaminated work clothing
should not be allowed out of the workplace.
P280 - Wear protective gloves/protective
clothing/eye protection/face protection
Precautionary Statements - Response:
P321
– Specific treatment (see Section 4/ First Aid).
P302 + P352 – IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 – If skin irritation or rash occurs: Get medical
attention.
P363 – Wash contaminated
clothing before reuse.
P304 +
P340 – IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 – Call a POISON CENTER or doctor
if you feel unwell.
Precautionary Statements - Storage:
P403 + P233 - Store
in a well-ventilated place. Keep container tightly closed.
Precautionary Statements - Disposal:
P501 - Dispose of contents/container to an
approved waste disposal plant
Hazards
not otherwise classified (HNOC):
Not applicable.
3.COMPOSITION/ INFORMATION ON INGREDIENTS
| Chemical Name | CAS No | Weight-% |
|
Permethrin | 52645-53-1 | 0.50 |
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Comments: Ingredients
not identified are proprietary or non-hazardous. Values are not product specifications.
4. FIRST AID
MEASURES
Aspiration pneumonia hazard: No information available.
Description of first aid measures:
Eye contact:
Hold
eye open and rinse slowly and gently with water for 15-20 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call
a
poison control center or doctor for treatment advice.
Skin
Contact:
Take
off contaminated clothing. Rinse skin immediately with plenty of water
for
15-20 minutes. Call a poison control center or doctor for treatment advice.
Ingestion:
If
swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. Have
person sip a glass of water if able to swallow. Do not induce vomiting unless told to
do so by a poison control center or a doctor. Never give anything by mouth to an unconscious person.
Inhalation:
Remove
affected person to fresh air. If person is not breathing, call 911 or
an ambulance, then give artificial respiration, preferably mouth-to-mouth
if possible. Call a poison control center or doctor for further treatment advice.
Self-protection of the First Responder:
Use personal protective equipment as required.
Note to physicians:
For skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroid exposure is topical application of tocopherol acetate (Vitamin E).
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing
measures that are appropriate to local circumstances and the surrounding environment
Unsuitable extinguishing media:
Caution: Use of water
spray when fighting fire may be inefficient.
Hazardous
combustion products:
Carbon monoxide. Carbon dioxide , Hydrogen chloride.
Specific
hazards arising from the chemical: No information available.
Explosion data
Sensitivity to Mechanical Impact: None.
Sensitivity to Static Discharge: None.
Protective equipment and precautions for firefighters:
As in any fire, wear self-contained breathing
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent)
and full protective gear.
NFPA
Health hazards 2 Flammability
1 Instability
0 Physical and
Chemical Properties
-
HMIS
Health hazards 1
Flammability 1
Physical hazards 0 Personal protection X
Chronic Hazard Star Legend
* = Chronic Health Hazard
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions:
Use personal protective equipment as required.
Evacuate personnel to safe areas. Keep people away from and upwind of
spill/leak..
Environmental
precautions: Prevent further leakage or spillage if safe to do so.
Do not allow into any sewer, on the ground or into any body of water.
Prevent product from entering drains. Local authorities should be advised if
significant
spillages cannot be contained.
See Section 12 for additional ecological information.
Methods and material for containment and cleaning up
Methods for containment:
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up: Dam
up. Soak up with inert absorbent material. Pick up and transfer to properly
labeled containers. Clean contaminated surface thoroughly.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling:
Use personal protective equipment as required.
Ensure adequate ventilation, especially in confined areas.
Use with local exhaust ventilation.
Do not breath fume/mist/vapor/spray.
For more information, see product label.
Conditions for safe storage, including any incompatibilities
Storage Conditions:
Keep
container tightly closed in a
dry and well-ventilated place.
Keep in properly labeled
containers.
For more information, see product label.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
Control parameters
Exposure Guidelines:
This product, as supplied, does not contain any hazardous materials with
occupational
exposure limits established by the
region specific regulatory bodies.
Appropriate engineering controls
Engineering Controls:
Safety showers Eyewash stations
Ventilation systems
Individual
protection measures, such as personal protective equipment
Eye/face protection:
Tight sealing safety goggles. Face protection shield.
Skin and body protection: Wear protective gloves and protective clothing.
Respiratory protection:
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA
approved respiratory protection should be worn. Positive-pressure supplied air
respirators may be
required for high airborne contaminant concentrations.
Respiratory protection must be provided in accordance with current local regulations.
General Hygiene
When using do not eat, drink or
smoke. Regular cleaning of equipment, work area Considerations:
and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties:
Physical state:
Liquid
Appearance:
Milky white
Odor:
Slight
solvent
Odor threshold:
No information
available
Color (Gardner Scale): No information
available
Property:
Values:
Comment: • Method
pH:
7.5
Melting point / freezing point:
No information available
Boiling point / boiling range:
No
information available
Flash point:
93.3°C /
>220 °F
Tag Closed
Cup
Flame Extension Test: No
information available
Evaporation rate:
No information available
Flammability (solid, gas): No information available
Upper flammability limit (UEL): No information available
Lower flammability limit (LEL): No information available
Vapor pressure:
No information available
Vapor density:
Heavier than air.
Specific Gravity:
8.3 lbs./ gal.
Partition coefficient; n-Octanol/ 6.5
Water:
Autoignition temperature:
No
information available
Decomposition temperature:
No information available
Kinematic viscosity:
No
information available
Dynamic viscosity:
6.83 cPs
@ 23.0 °C
Refractive Index:
No information available
Other Information:
Density:
0.999 g/cm3 @ 20 °C
VOC Content (%):
0.08
Miscibility/ Solubility:
Water:
Partially
miscible
Alcohol:
Miscible
Petroleum distillates:
Immiscible
Aromatic solvents:
Immiscible
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None
under normal processing.
Hazardous polymerization:
Hazardous polymerization does not occur.
Conditions
to avoid
Extremes of temperature and direct sunlight.
Incompatible materials:
Incompatible with strong acids and bases. Incompatible with oxidizing agents.
Hazardous Decomposition
Products
Hydrogen chloride, Carbon monoxide, Carbon dioxide (CO2)
11. TOXICOLOGICAL INFORMATION
Numerical measures of toxicity - Product Information
Oral LD50
>5,000 mg/kg (rat)
Dermal LD50
>2,000 mg/kg (rabbit)
Inhalation LC50
>2.05 mg/L (rat; 4 hours)
Eye contact:
Non
irritating to eyes . (rabbit)
Skin Contact:
Non irritating at 72 hours . (rabbit)
Skin Irritation Index:
0.40
Sensitization:
Negative. (guinea pig).
Comment:
Toxicology data was
bridged from a similar formula.
Carcinogenicity
This
product does not contain any carcinogens or potential carcinogens as listed
by OSHA, IARC or NTP
Reproductive
toxicity:
No information available.
Developmental Toxicity No information available.
Teratogenicity:
No information available.
STOT - single
exposure: No information available.
STOT - repeated exposure: No
information available
Chronic toxicity:
Avoid repeated exposure
12.
ECOLOGICAL INFORMATION
Ecotoxicity:
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Other adverse effects: No information available
Environmental hazards
(EPA):
Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other
waters unless
in accordance with the requirements of a
National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been
notified in writing prior to discharge. Do not
discharge effluent containing this product to sewer systems
without previously notifying the local sewage treatment plant authority. For guidance contact your
State Water Board or Regional Office of the
EPA.
13.
DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes:
Disposal should be in accordance with applicable regional, national and local laws
and regulations. For more information, see product label.
Contaminated packaging:
For more information, see product label.
14. TRANSPORT INFORMATION
DOT (Department of Transportation)
Proper Shipping Name:
Insecticides, Insect or Animal Repellent, Liquid
Hazard Class:
Non-Hazardous
Air (IATA/ ICAO)
Proper Shipping Name:
Insecticides, Insect or Animal Repellent, Liquid
Hazard Class:
Non-Hazardous
Vessel (IMO/ IMDG)
Proper Shipping Name:
Not available
15. REGULATORY INFORMATION
US Federal Regulations
SARA 313
Section 313 of Title III
of the Superfund Amendments and Reauthorization Act of
1986 (SARA). This product does not contain any chemicals which are subject to the
reporting requirements of the Act
and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute health hazard
No
Chronic Health Hazard
No
Fire hazard
No
Sudden release of pressure hazard
No
Reactive Hazard
No
CWA (Clean Water Act)
This
product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR
122.21 and 40 CFR
122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the
Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the
Superfund Amendments and
Reauthorization Act (SARA) (40 CFR
355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
US State Regulations:
California
Proposition 65:
This product does not contain any Proposition 65 chemicals
U.S. EPA Label Information:
EPA Registration Number: 1021-1740-84396
Difference between SDS and EPA (FIFRA) Pesticide label:
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject
to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria
and hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals. The pesticide label also includes other important information, including directions for use.
The hazard information
required on the pesticide label is reproduced below:
Signal word: CAUTION
Precautionary Statements: Harmful if inhaled.
Harmful if absorbed through the skin.
International:
TSCA
Does not comply
DSL/NDSL
Does not comply
EINECS/ELINCS
Complies
ENCS
Complies
IECSC
Complies
KECL
Does not comply
PICCS
Does not comply
AICS
Does not comply
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances
List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical
Substances
ENCS -
Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION.
Issue Date:
25-Jun-2015
Revision Date:
25-Jun-2015
Revision Note:
New SDS. GHS - Classification.
SDS Prepared By:
Regulatory Department.
Disclaimer:
The
data contained herein are based on information currently available to Sungro Products, LLC and,to the best of our knowledge, are accurate and
based on sound expert opinion. Our statements herein, however, are not
to be taken as a warranty or representation for which Sungro Products, LLC
assumes legal responsibility.
End of Safety Data Sheet.
