SAFETY
DATA SHEET (SDS)
SUN-
DUST ROACH AWAY
Manufactured : SUNGRO PRODUCTS
Issue Date: 13-Apr-2015
810 E. 18TH ST.
LOS ANGELES, CA
90021
Tel: 213-747-4125
Fax: 213-747-0942
E: sales@sungroproducts.com
This Material Safety Data Sheet contains environmental, health
and toxicology information for your employees. Please make sure this information is given to them. It also contains information
to help you meet community Right To Know emergency response reporting requirements under SARA TITLE III and many other laws.
If you resell this product, this SDS must be given to the buyer or the information incorporated in your SDS.
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
Product Name:
SUN-DUST ROACH AWAY
EPA Registration Number:
1021-1665-84396
Other means
of identification
Recommended
use of the chemical and restrictions on use: Recommended
Use:
Insecticide.
Details of the
supplier of the safety data sheet
Manufacturer Address:
Sungro Products, LLC.
810 E. 18th St.
Los Angeles, CA
90021
FAX #: (213)747-0942
Telephone
Number: (800)463-9179, or (213) 747-4125
e-Mail Address:
sales@sungroproducts.com
Emergency telephone
numbers:
24 Hour TRANSPORTATION Emergency: INFOTRAC®: (800) 535-5053 - Contract #78479
International:
(352) 323-3500
24 Hour MEDICAL Emergency: Safety Call®: (888) 740-8712, or (952)
852-9509
Comments:
SUNGRO PRODUCTS
Hours of operation are 7:30 am to 4:00 pm PCT.
For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to
(888) 740-8712, or (952) 852-9509.
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status:
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Label elements
Emergency Overview
Hazard statements
• H333 - May be harmful if inhaled
• H402 - Harmful to aquatic life
•
H412 - Harmful to aquatic life with long lasting effects
Appearance: White
Physical state: Solid - Powder
Odor: Sweet
Precautionary Statements
- Prevention:
P202
- Do not handle until all safety precautions have been read and understood
P273 - Avoid release to the environment
Precautionary Statements - Response:
P305 + P351
+ P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Precautionary Statements - Storage:
P403 + P233 - Store in a
well-ventilated place. Keep container tightly closed
Precautionary
Statements - Disposal:
P501 - Dispose of contents/container
to an approved waste disposal plant
Hazards not otherwise classified (HNOC):
Not applicable.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
| Chemical Name
|
CAS No
|
Weight-% |
| Pyrethrins | 8003-34-7 | 1.00 |
| Piperonyl
Butoxide (PBO) | 51-03-6
|
10 |
| Silicon Dioxide | 7631-86-9 | 60 |
|
Glycerin | 56-81-5 | 20<--->30
* |
| Petroleum distillates, hydrotreated light |
64742-47-8 | < 5 |
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications.
4. FIRST AID MEASURES
Aspiration pneumonia hazard:
• No information available
Description of first aid measures:
Eye contact:
Hold
eye open and rinse slowly and gently with water for 15-20 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call
a
poison control center or doctor for treatment advice.
Skin
Contact:
Take
off contaminated clothing. Rinse skin immediately with plenty of water
for
15-20 minutes. Call a poison control center or doctor for treatment advice.
Ingestion:
If
swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. DO NOT give
any liquid to
the person. Do not induce vomiting unless told to do so by a poison control center or a doctor. Never give anything by mouth to an unconscious person.
Inhalation:
Remove
affected person to fresh air. If person is not breathing, call 911 or
an ambulance, then give artificial respiration, preferably mouth-to-mouth
if possible. Call a poison control center or doctor for further treatment advice.
Self-protection of the First Responder:
Use personal protective equipment as required.
Note to physicians:
For
skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroid
exposure is topical application oftocopherol acetate (Vitamin E).
5.
FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media:
Caution: Use of water spray when fighting fire may be inefficient.
Hazardous combustion products: Carbon monoxide. Carbon dioxide (CO2).
Specific hazards arising from the chemical
No information available.
Explosion data
Sensitivity to Mechanical Impact: None.
Sensitivity
to Static Discharge: None.
Protective equipment and precautions for firefighters:
As in any fire, wear self-contained breathing
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent)
and full protective gear.
NFPA
Health hazards 2 Flammability 1
Instability 0
Physical
and Chemical Properties
-
HMIS
Health hazards 1 *
Flammability 1
Chronic Hazard Star Legend
* = Chronic Health Hazard
Physical hazards 0
Personal protection
X
6. ACCIDENTAL RELEASE
MEASURES
Personal
precautions, protective equipment and emergency procedures
Personal precautions:
Evacuate personnel to safe areas. Keep people away from and
upwind of
spill/leak. Use personal protective equipment as required.
Environmental
precautions: Prevent
further leakage or spillage if safe to do
so. Prevent product from entering
drains. See Section 12 for
additional ecological information.
Methods and material for containment and cleaning up
Methods for containment: Prevent further leakage or spillage if safe to do so.
Methods for cleaning up:
Use personal protective equipment as required. Cover powder spill with plastic
sheet or tarp to minimize spreading and keep powder dry. Take
up mechanically,
placing in appropriate containers for disposal. Avoid creating dust. Clean contaminated surface thoroughly. Dam up. Soak up
with inert absorbent material. Pick up and transfer to properly labeled containers.
7.
HANDLING AND STORAGE
Precautions for safe
handling
Advice on safe handling:
Use with local exhaust ventilation. Use personal protective equipment as required.
Do not breathe dust/fume/gas/mist/vapors/spray. For more information, see
product label.
Conditions for safe storage, including any incompatibilities
Storage Conditions:
Keep
containers tightly closed in a
cool, well-ventilated place. Keep in
properly
labeled containers.
For more information, see product label.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
Control parameters
Exposure Guidelines:
This product, as supplied, does not contain any hazardous materials with
occupational exposure limits established by the
region specific regulatory bodies.
| Chemical Name | ACGIH TLV | OSHA PEL | NIOSH IDLH |
| Pyrethrins 8003-34-7 | TWA: 5 mg/m3 | TWA: 5 mg/m3 (vacated) TWA: 5
mg/m3 | IDLH: 5000 mg/m3 TWA: 5 mg/m3 |
|
Silicon Dioxide 7631-86-9
|
- | (vacated) TWA: 6 mg/m3 <1% Crystalline silica TWA: 20 mppcf : (80)/(% SiO2) mg/m3 TWA |
IDLH: 3000
mg/m3 TWA: 6 mg/m3 |
|
Glycerin 56-81-5
|
- | TWA: 15 mg/m3 mist, total particulate TWA: 5 mg/m3 mist, respirable fraction (vacated) TWA: 10 mg/m3 mist, total particulate
(vacated) TWA: 5 mg/m3 mist,
respirable fraction | -
|
NIOSH IDLH Immediately Dangerous to Life or
Health
Other Information:
Vacated limits revoked by the
Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Appropriate engineering controls
Engineering Controls:
Safety showers Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection:
Tight sealing safety goggles. Face protection shield.
Skin and body protection: Wear protective gloves and protective clothing.
Respiratory protection:
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA
approved respiratory protection should be worn. Positive-pressure supplied air
respirators may be required for high
airborne contaminant concentrations.
Respiratory protection must be provided in accordance with current local regulations.
General Hygiene
Considerations:
When using,do not eat, drink or smoke.
Regular cleaning of equipment, work area
and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties:
| Physical state: Appearance: Odor: Odor threshold: Color (Gardner Scale): | Solid - Powder White Sweet No information available No information available | |
| Property: pH: Melting point / freezing point: |
Values: 6.6 No information available |
Comment: • Method @ 20% in H2O.
|
|
Boiling point / boiling range:
| No information available |
|
|
Flash point: Flame Extension Test: | > 93.3 °C / > 200.0 °F No information available
| Tag Closed Cup |
| Evaporation rate: | No information available | |
| Flammability
(solid, gas): | No information available | |
| Upper flammability limit (UEL): Lower flammability limit (LEL): Vapor pressure: | No information available
No information available
No information available
|
|
|
Vapor density: |
Heavier than air. | |
| Specific Gravity: | No information available | |
| Partition coefficient; n-Octanol/
| No information available |
|
| Water:
Autoignition temperature: | No information available | |
| Decomposition
temperature: | No information available | |
| Kinematic viscosity:
| No information available |
|
|
Dynamic viscosity:
| No information available |
|
|
Refractive Index:
| No information available | @ 25°C (77°F)
|
|
Other Information:
|
|
|
|
Bulk density | 0.304 | |
| VOC Content (%):
| 25
|
|
|
Miscibility/ Solubility: Water: |
Partially miscible | |
| Alcohol: Petroleum distillates: Aromatic solvents:
| Immiscible Immiscible Immiscible | |
10.
STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous
polymerization: Hazardous polymerization does not
occur.
Conditions to avoid
Extremes of temperature and direct sunlight.
Incompatible materials:
Incompatible with strong acids and
bases. Incompatible with oxidizing agents.
Hazardous Decomposition Products
Carbon monoxide, Carbon dioxide (CO2)
11. TOXICOLOGICAL INFORMATION
Numerical measures of toxicity - Product Information
Oral LD50
>5,000 mg/kg (rat)
Dermal LD50
>2,000 mg/kg (rabbit)
Inhalation LC50
>5.40 mg/L (rat; 4 hours)
Eye contact:
Irritation clearing in 48 hours.
Skin Contact:
No irritation observed.
Skin Irritation Index:
0.0
Sensitization:
Negative. (guinea pig).
Piperonyl Butoxide: Carcinogenicity/ Oncogenicity:
Marginally higher incidences of benign liver tumors in mice were observed
following lifetime high dose exposures to PBO. The significance of these observations is questionable and under review. The doses at which tumors were observed for PBO
greatly exceeded potential human exposure from labeled uses.
Doses at which these effects were observed greatly exceeded anticipated human
dietary intake. At anticipated dietary exposure levels, it is highly unlikely that this product will result in carcinogenic effects.
Carcinogenicity
This
product does not contain any carcinogens or potential carcinogens as listed
by OSHA, IARC or NTP.
Reproductive
toxicity:
No information available.
Developmental Toxicity
No information available.
Teratogenicity:
No information available.
STOT - single exposure:
No information available.
STOT - repeated exposure:
No information available.
Chronic toxicity:
Avoid repeated exposure.
Neurological effects:
No information available.
Target Organ Effects:
Central nervous system, Eyes, kidney, Respiratory system, Skin.
12. ECOLOGICAL INFORMATION
Ecotoxicity:
Persistence and degradability
No information available.
Bioaccumulation
No information available.
| Chemical Name
|
Partition coefficient; n-Octanol/ Water: |
| Glycerin 56-81-5 |
-1.76 |
Other adverse effects: No information available
Environmental hazards
(EPA):
Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other
waters unless
in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting
authority has been notified in writing prior to
discharge. Do not discharge effluent containing this product to sewer systems
without previously notifying the local sewage treatment plant authority. For guidance contact your
State Water Board or Regional Office of the
EPA.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes:
Disposal should be in accordance with applicable regional, national and local laws
and regulations. For more information, see product label.
Contaminated packaging:
For more information, see product label.
14. TRANSPORT INFORMATION
DOT (Department of Transportation)
UN/ID Number:
UN3077
Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s., RQ (Pyrethrins)
Hazard Class:
9
Packing Group:
III
Reportable Quantity (RQ):
Pyrethrins (1 Lb.)
Other Shipping Information: This material is not regulated as a hazardous material by the DOT in quantities
less than 100
Lbs.
Shipping name for quantities less than 100 Lbs.:
Insecticides, Insect or Animal Repellent, Solid
Air (IATA/ ICAO)
UN/ID Number:
UN3077
Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s., RQ (Pyrethrins)
Hazard Class:
9
Packing Group:
III
Vessel (IMO/ IMDG)
UN/ID Number:
UN3077
Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s., RQ (Pyrethrins)
Hazard Class:
9
Packing Group:
III
15. REGULATORY INFORMATION
US Federal Regulations
SARA 313
Section 313 of Title III
of the Superfund Amendments and Reauthorization Act of
1986 (SARA). This product contains
a chemical or chemicals which are subject to the
reporting requirements of the Act
and Title 40 of the Code of Federal Regulations, Part 372
| Chemical Name |
SARA 313 - Threshold Values % |
| Piperonyl Butoxide (PBO) - 51-03-6
|
1.0 |
SARA 311/312 Hazard Categories
Acute health hazard
No
Chronic Health Hazard
No
Fire hazard
No
Sudden release of pressure hazard
No
Reactive Hazard
No
CWA (Clean Water Act)
This
product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR
122.21 and 40 CFR
122.42)
| Chemical Name | CWA - Reportable
Quantities | CWA - Toxic Pollutants |
CWA - Priority Pollutants | CWA - Hazardous
Substances |
| Pyrethrins 8003-34-7
|
1 lb
|
- | - | - |
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the
Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the
Superfund Amendments and
Reauthorization Act (SARA) (40 CFR
355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
| Chemical Name | Hazardous Substances RQs |
CERCLA/SARA RQ | Reportable Quantity (RQ):
|
| Pyrethrins 8003-34-7
|
1 lb | - | RQ 1 lb final
RQ RQ 0.454 kg final RQ |
US State Regulations:
California Proposition 65:
This product does not contain any Proposition 65 chemicals
U.S. EPA Label Information:
EPA Registration Number: 1021-1665-84396
Difference between SDS and EPA (FIFRA) Pesticide label:
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject
to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria
and hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals. The pesticide label also includes other important information, including directions for use.
The hazard information
required on the pesticide label is reproduced below:
Signal word:
CAUTION
Precautionary Statements:
• Harmful if absorbed through the skin.
International:
TSCA
Complies
DSL/NDSL
Complies
EINECS/ELINCS
Complies
ENCS
Does not comply
IECSC
Complies
KECL
Complies
PICCS
Complies
AICS
Complies
Legend:
TSCA
- United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL -
Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical
Substances
ENCS -
Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
1. OTHER INFORMATION,
INCLUDING DATE OF PREPARATION OR LAST REVISION.
Issue Date:
06-Apr-2015
Revision Date:
06-Apr-2015
Revision Note:
New SDS. GHS - Classification.
SDS Prepared By:
Disclaimer:
The
data contained herein are based on information currently available to Sungro Products, LLC and,to the best of our knowledge, are accurate and
based on sound expert opinion. Our statements herein, however, are not
to be taken as a warranty or representation for which Sungro Products, LLC
assumes legal responsibility.
End of Safety Data Sheet.
