SAFETY DATA SHEET Supersedes Revision: 11/11/2013 Product Code: QT2600 Product Name: SADD Sanitary Acid Descaler Company Name: Winner Industrial Supply 154 "A" Foothill Blvd #149 Upland, CA 91786 Emergency Contact: infotrac #107557 (800)535-5053 Information: vincent@winnerchemicals.com (909)886-9466 Recommended Use: Toilet Bowl Cleaner Intended Use: For sale to, use and storage by service persons only. 1. Product and Company Identification 2. Hazards Identification Do not breathe dust, fumes, mist, vapors, spray. Wash hands thoroughly after handling. Wear protective gloves, protective clothing, eye protection, face protection. Use only outdoors or in a well-ventilated area. Avoid breathing fumes and spray mist. GHS Precaution Phrases: If on skin (or in hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If swallowed: Rinse mouth. Do NOT induce vomiting. If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if exposed or you feel unwell. GHS Response Phrases: Dispose of contents and container according to the local, city, state and federal regulations. Store in cool dry place at room temperature away from direct sunlight. GHS Storage and Disposal Phrases: Causes severe skin burns and eye damage. May cause respiratory irritation. GHS Hazard Phrases: Skin Corrosion/Irritation, Category 1B Target Organ Systemic Toxicity (single exposure), Category 3 GHS Signal Word: Danger Potential Health Effects (Acute and Chronic): Corrosive to the eyes and may cause severe damage including blindness. Avoid any eye contact. Eye Contact: Skin Contact: Corrosive, causes permanent skin damage (scarring). Avoid any skin contact. Corrosive and may cause severe and permanent damage to mouth, throat, and stomach. Poison - may be fatal if swallowed. Ingestion: Causes respiratory tract irritation. May be harmful if inhaled. Avoid breathing vapors or mists. Inhalation: GHS format Revision: 02/25/2015 Printed: 07/07/2015 Page: 2 SADD Sanitary Acid Descaler SAFETY DATA SHEET Supersedes Revision: 11/11/2013 CAS # Hazardous Components (Chemical Name) 3. Composition/Information on Ingredients Concentration 7647-01-0 Hydrochloric acid Proprietary In Case of Inhalation: 4. First Aid Measures Emergency and First Aid Procedures: Note to Physician: Treat symptomatically and supportively. Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. In Case of Eye Contact: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. In Case of Skin Contact: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. In Case of Ingestion: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. 5. Fire Fighting Measures Flash Pt: NA As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Fire Fighting Instructions: Flammable Properties and No data available. Hazards: Autoignition Pt: NA Explosive Limits: LEL: N/A N.E. UEL: N/A N.E. Suitable Extinguishing Media:Use water spray, dry chemical, carbon dioxide, or chemical foam. 6. Accidental Release Measures Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Steps To Be Taken In Case Material Is Released Or Spilled: 7. Handling and Storage Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse. Precautions To Be Taken in Handling: Precautions To Be Taken in Store in a cool, dry, well-ventilated area away from incompatible substances. Storing: 8. Exposure Controls/Personal Protection GHS format Revision: 02/25/2015 Printed: 07/07/2015 Page: 3 SADD Sanitary Acid Descaler SAFETY DATA SHEET Supersedes Revision: 11/11/2013 CAS # Partial Chemical Name OSHA TWA ACGIH TWA Other Limits 7647-01-0 Hydrochloric acid CEIL: 5 ppm CEIL: 2 ppm) No data. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Respiratory Equipment (Specify Type): Eye Protection: Wear chemical splash goggles. Protective Gloves: Wear appropriate protective gloves to prevent skin exposure. Other Protective Clothing: Wear appropriate protective clothing to prevent skin exposure. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Engineering Controls (Ventilation etc.): 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: NE Boiling Point: >= 212.00 F Decomposition Temperature: NE Autoignition Pt: NA Flash Pt: NA Explosive Limits: LEL: N/A N.E. UEL: N/A N.E. Specific Gravity (Water = 1): 1.125 Density: 9.38 lbs/gal Appearance and Odor: Opaque white liquid with acrid fragrance. Bulk density: NE Vapor Pressure (vs. Air or mm Hg): NE Vapor Density (vs. Air = 1): > 1 Evaporation Rate: NE Solubility in Water: 100% Percent Volatile: No data. VOC / Volume: 0.0000 GL Saturated Vapor Concentration: NE Viscosity: NP pH: 0.5 - 2.0 Heat Value: NE Particle Size: NE Corrosion Rate: NE GHS format Revision: 02/25/2015 Printed: 07/07/2015 Page: 4 SADD Sanitary Acid Descaler SAFETY DATA SHEET Supersedes Revision: 11/11/2013 10. Stability and Reactivity Conditions To Avoid - None. Instability: Stability: Unstable [ ] Stable [ X ] Incompatibility - Materials To Strong oxidizers, ammonia, chlorine, strong alkali materials, aluminum. Avoid: Hazardous Decomposition Or CO, CO2. Byproducts: Possibility of Hazardous Will occur [ ] Will not occur [ X ] Reactions: Conditions To Avoid - None. Hazardous Reactions: CAS # Hazardous Components (Chemical Name) NTP 11. Toxicological Information Toxicological Information: No data available. Carcinogenicity/Other CAS# 7647-01-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Information: IARC ACGIH OSHA 7647-01-0 Hydrochloric acid n.a. 3 A4 n.a. No data available. 12. Ecological Information CAS# 7647-01-0: Effective concentration to {0} % of test organisms, Brook Trout (Salvelinus fontinalis), 10000. UG/L, Mortality, Water temperature: 11.70 C - 15.60 C C. Results: No observed effect. - Toxicity Experiments with Fish in Reference to Trade Waste Pollution. I. The Problem of Water Pollution, Belding, D.L., 1927 LC50, Western Mosquitofish (Gambusia affinis), adult(s), 282000. UG/L, 96 H, Mortality, Water temperature: 21.00 C - 23.00 C C, pH: 8.20. Results: Morphological changes. - Toxicity to Gambusia affinis of Certain Pure Chemicals in Turbid Waters, Wallen, I.E., W.C. Greer, and R. Lasater, 1957 LC50, Western Mosquitofish (Gambusia affinis), adult(s), 282000. UG/L, 24 H, Mortality, Water temperature: 21.00 C - 23.00 C C, pH: 8.20. Results: No observed effect. - Toxicity to Gambusia affinis of Certain Pure Chemicals in Turbid Waters, Wallen, I.E., W.C. Greer, and R. Lasater, 1957 Results of PBT and vPvB assessment: GHS format Revision: 02/25/2015 Printed: 07/07/2015 Page: 5 SADD Sanitary Acid Descaler SAFETY DATA SHEET Supersedes Revision: 11/11/2013 Dispose of contents and container according to the local, city, state and federal regulations. Waste Disposal Method: 13. Disposal Considerations 14. Transport Information Corrosive liquids, n.o.s. Quart: Limited quantity. Gallon or higher: NA1760, Compounds, Cleaning Liquid, (Contains Hydrochloric Acid), 8, II. (Hydrochloric acid) DOT Proper Shipping Name: DOT Hazard Class: 8 CORROSIVE UN/NA Number: UN1760 Packing Group: II LAND TRANSPORT (US DOT): 15. Regulatory Information CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 7647-01-0 Hydrochloric acid CAA HAP,ODC: HAP; CWA NPDES: No; TSCA: Yes - Inventory, 4 Test; CA PROP.65: No; CA TAC, Title 8: TAC, Title 8 16. Other Information Additional Information About No data available. This Product: Hazard Rating System: Instability Special Hazard Health Flammability HEALTH FLAMMABILITY PPE PHYSICAL The manufacturer believes the data set forth are accurate and makes no warranty with respects thereto and disclaims all liability for reliance thereon. Such data are offered solely for consideration, investigation and verification. Also, the data set forth is for the concentrated finished product. All lab samples are for experimental purposes only and used at the customers discretion. Company Policy or Disclaimer: 3 0 0 D 3 0 0 Revision Date: 02/25/2015 HMIS: NFPA: GHS format